Mobile photovoltaic (PV) power systems provide a flexible electricity supply for remote locations, emergency operations, and other off-grid applications. Their practical operation requires continuous assessment of power conversion performance under changing environmental conditions. This study investigates the efficiency, power output, and operational reliability of a mobile PV system through an Internet of Things (IoT)-enabled monitoring platform and a multilayer perceptron (MLP) model. Solar irradiance, panel temperature, voltage, current, power, and battery state of charge (SOC) were recorded under outdoor operating conditions, yielding approximately 1,600 observations. An MLP with two hidden layers was trained using the Levenberg–Marquardt algorithm, and the data were divided into training and testing subsets at a ratio of 80:20. Operational reliability was evaluated by comparing measured and predicted power outputs against statistically defined control limits. The PV panel achieved an average operating efficiency of approximately 15%, whereas the efficiency of the solar charge controller (SCC) reached 60%. For the normalized dataset, the MLP produced mean squared error (MSE) values of 0.002402 and 0.001951, root mean squared error (RMSE) values of 0.049012 and 0.044173, mean absolute error (MAE) values of 0.033774 and 0.027760, and $R^2$ values of 0.964491 and 0.970248 for PV and controller power, respectively. The predicted outputs remained within the established control limits throughout the observation period. These findings indicate that the proposed framework can support real-time power-performance assessment and the early identification of abnormal operating conditions in mobile PV systems.