For reducing uncertainty in data gathered from real-world scenarios, the picture fuzzy rough set (PFRS) framework is a reliable resource. This article presents new aggregation operators (AOs) based on the Schweizer-Sklar t-conorm (SS-TC) and Schweizer-Sklar t-norm (SS-TN). They present the PFRS framework with SS, which aims to handle the intricacies in contexts where decision-making is marked by ambiguity and uncertainty. In the context of Green Supply Chain Management (GSCM), where supply chain procedures incorporate sustainability considerations, this framework is especially pertinent. GSCM places a strong emphasis on minimizing environmental impacts by employing techniques such as effective resource management and sustainable sourcing. The adaptability and versatility required to assess and optimize these inexperienced practices are significantly improved with the aid of our expert PFRS framework. Businesses can keep operational efficiency and align their supply chain operations with environmental desires with the aid of using this framework. By considering both the blessings and disadvantages of environmental sustainability, using PFRS in GSCM enhances decision-making and promotes environmental sustainability. To handle picture fuzzy rough values (PFRVs), these operators include picture fuzzy rough weighted averaging (PFRSSWA) and picture fuzzy rough weighted geometric (PFRSSWG) operators. We investigate these recently created AOs' basic characteristics and use them to solve multi-attribute group decision-making (MAGDM) issues under the framework of picture fuzzy (PF) data. Our results demonstrate how the outcomes in SS-TN and SS-TC vary with varying parameter values. We also contrast these outcomes with the ones obtained from pre-existing AOs. In addition, we provide a graphic representation of all observations and findings to show how flexible and successful the suggested operators are at handling MAGDM problems.