This study presents a comprehensive numerical analysis aimed at determining the enhanced combustion rate, burning velocity, and laminar flame speed of premixed LPG/air mixtures. Different values of equivalence ratios (ER) were considered between 0.6 and 1.4. The analyses were conducted at initial conditions of 1.0 atm and 300 K inside a horizontal cylindrical combustion chamber (CCC). Simulations were performed using ANSYS Fluent and Chemkin USC Mechanics 2.0 software, which effectively predicted flame characteristics. The results indicate that the stoichiometric mixture gives the highest extended laminar flame velocity of 288.88 cm/s, followed by the lean mixture, ER = 0.6, with 84.1 cm/s, and the rich mixture, ER = 1.4, with 118.66 cm/s. The observed combustion rates of the stoichiometric, lean, and rich mixtures were 14.9, 37, and 18.5 cm/s, respectively. Also, the laminar burning velocity for pure propane and pure butane at different ERs, of 0.6, 0.8, 1.0, 1.2, and 1.4, were 19.4, 36.9, 45, 42.1, and 25.1 for propane mixtures, and 14.8, 29, 36.5, 33.4, and 18.4 for butane mixtures, respectively. For the same aforementioned ER, the measured laminar flame velocities were 87.55, 200.9, 274.1, 238.9, and 116.67 cm/s, respectively, and the laminar combustion velocities were 15.2, 28.7, 35.5, 33, and 18.2 cm/s, respectively, with a 2.8% gain margin. Moreover, for naphtha fuel vapors, laminar combustion velocities of 32.16, 41.2, 49.45, 46, and 28.6 cm/s for ERs of 0.6, 0.8, 1, 1.2, and 1.4. The numerical results of the ILPG (Iraq liquefied petroleum gas) show that the maximum stretched laminar flame speed reached 288.88 cm/s at ER = 1.0, while with ER = 0.6, it is 84.1 cm/s, and with ER = 1.4, it is 118.66 cm/s. Compared to ILPG, propane, and butane, Naphtha burns faster.