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[1] Sharf Ilahi Siddiqui, S.A.C., Iron oxide and its modified forms as an adsorbent for ar-senic removal: A comprehensive recent advancement. Process Safety and Environment Protection, 111, pp. 592–626, 2017.
[2] Kao, A.C., Chu, Y.J., Hsu, F.L. & Liao, V.H.C., Removal of arsenic from groundwater by using a native isolated arsenite-oxidizing bacterium. Journal of Contaminant Hy-drology, 155, pp. 1–8, 2013.
[3] Ng, J.C., Wang, J. & Shraim, A., Global health problems caused by arsenic from natural sources. Chemosphere, 52, pp. 1353–1359, 2003.
[4] *** WHO, Arsenic in drinking water, World Health Organization, 2011 http://www. who.int/water_sanitation_health/dwq/chemicals/arsenic.pdf (accessed 30 November 2017).
[5] Ramesh, A., Hasegawa, H., Maki, T. & Ueda, K., Adsorption of inorganic and organic arsenic from aqueous solutions by polymeric Al/Fe modified montmorillonite. Separa-tion and Purification Technology, 56, pp. 90–100,2007.
[6] Guo, H., Stuben, D. & Berner, Z., Arsenic removal from water using natural iron min-eral quartz sand columns. Science of the Total Environment, 377, pp. 142–151, 2007.
[7] Kundu, S. & Gupta, A.K., Adsorptive removal of As(III) from aqueous solution using iron oxide coated cement (IOCC): Evaluation of kinetic, equilibrium and thermody-namic models. Separation and Purification Technology, 51, pp. 165–172, 2006.
[8] Borah, D., Satokawa, S., Kato, S. & Kojima, T., Surface–modified carbon black for As(V) removal. Journal of Colloid and Interface Science, 319, pp. 53–62, 2008.
[9] Mohan D. & P.J.C.U., Arsenic removal from water/wastewater using adsorbents—A critical review. Journal of Hazardous Materials, 142(1–2), pp. 1-53, 2007.
[10] Molinari R. & A.P., Arsenic removal from water by coupling photocatalysis and com-plexation-ultrafiltration processes: A preliminary study. Water research, 109, pp. 327–336, 2017.
[11] Bora A.J., G.S., Baruah G. & Dutta R.K., Utilization of co-existing iron in arsenic removal from groundwater by oxidation-coagulation at optimizated pH. Journal of En-vironmental Chemical Engineering, 4, pp. 2683–2691, 2016.
[12] Banerji T. & C.S., Arsenic removal from drinking water by electrocoagulation using iron electrodes – an understanding of the process parameters. Journal of Environmental Chemical Engineering, 4, pp. 3990–4000, 2016.
[13] Ji J., Y.Y., Zenga Z., Wanga R., Zhenga X., Deng L. & Li C., Preparation and arse-nic adsorption assessment of PPESK ultrafiltration membranes with organic/inorganic additives. Applied Surface Science, 351, pp. 715–724, 2015.
[14] Zhao D., Y.Y., Wang C. & Chen J.P., Zirconium/PVA modified flat-sheet PVDF mem-brane as a cost-effective adsorptive and filtration material: A case study on decon-tamination of organic arsenic in aqueous solutions. Journal of Colloid and Interface Science, 477, pp. 191–200, 2016.
[15] Salazar H., N.-P.J., Correia D.M., Cardoso V.F., Gonçalves R., Martins P.M., Ferdov S., Martins M.D., Botelho G. & Lanceros-Méndez S., Selective separation of elements from complex solution matrix with molecular recognition plus macrocycles attached to a solid-phase: A review. Materials Chemistry and Physics, 183, pp. 430–434, 2016.
[16] Lee C.G., A.P.J.J., Nam A., Park S.J., Do T., Choi U.S. & Lee S.H., Arsenic(V) removal using an amine-doped acrylic ion exchange fiber: Kinetic, equilibrium, and regenera-tion studies. Journal of Hazardous Materials, 123(1–3), pp. 223–229, 2017.
[17] Dhoble R. M. , M.P.R., Rayalu S. S., Bhole A.G. , Dhoble A. S. & Dhoble S. R., Removal of arsenic(III) from water by magnetic binary oxide particles (MBOP): Experimental studies on fixed bed column. Journal of Hazardous Materials, Part B, pp. 469–478, 2017.
[18] Vithanage M., H.I., Joseph S., Bundschuh J., Bolan N., Ok Y.S., Kirkham M.B. & Rinklebe J., Interaction of arsenic with biochar in soil and water: A critical review. Carbon, 113, pp. 219–230, 2017.
[19] Suda A. & T.M., Functional effects of manganese and iron oxides on the dynamics of trace elements in soils with a special focus on arsenic and cadmium: A review. Geoderma, 270, pp. 68–75, 2016.
[20] Lata S. & S.S.R., Removal of arsenic from water using nano adsorbents and challenges: A review. Journal of Environmental Management, 166, pp. 387–406 2016.
[21] Rahim M., H.M.R. & Haris M., Application of biopolymer composites in arsenic removal from aqueous medium: A review. Journal of Radiation Research and Applied Sciences, 8, pp. 255–263, 2015.
[22] Roy P., M.N.K. & Das K., Geochemistry and arsenic behaviour in groundwater re-sources of the Pannonian Basin (Hungary and Romania). Applied Geochemistry, 26(1), pp. 1–17, 2014.
[23] Abdel-Halim, E.S. & Al-Deyab S.S., Removal of heavy metals from their aqueous solutions through adsorption onto natural polymers. Carbohydrate Polymers, 84(1), pp. 454–458, 2011.
[24] Huang, Z., et al., A novel biodegradable β-cyclodextrin-based hydrogel for the removal of heavy metal ions. Carbohydrate Polymers, 97(2), pp. 496–501, 2013.
[25] Podder, M.S. & Majumder C.B., Bacteria immobilization on neem leaves/MnFe2O4 composite surface for removal of As(III) and As(V) from wastewater. Arabian Journal of Chemistry, 2015.
[26] Sheng, T., et al., Development, characterization and evaluation of iron-coated honey-comb briquette cinders for the removal of As(V) from aqueous solutions. Arabian Jour-nal of Chemistry, 7(1), pp. 27–36, 2014.
[27] Lavoine, N., et al., Microfibrillated cellulose – Its barrier properties and applications in cellulosic materials: A review. Carbohydrate Polymers, 90(2), pp. 735–764, 2012.
[28] Šimkovic, I., Unexplored possibilities of all-polysaccharide composites. Carbohydrate Polymers, 95(2), pp. 697–715, 2013.
[29] Schwaminger, S.P., et al., Nature of Interactions of Amino Acids with Bare Magnetite Nanoparticles. Journal of Physical Chemistry C, 119(40), pp. 23032–23041, 2015.
[30] Negrea, A., Popa, A., Ciopec, M., Lupa, L., Negrea, P., Davidescu, C. M., Motoc, M. & Mînzatu, V., Phosphonium grafted styrene–diviniylbenzene resins impregnated with iron (III) and crown ethers for arsenic removal, Pure and Applied Chemistry, 86(11), pp. 1729–1740, 2014.
[31] Ciopec, M., Hulka, I., Duţeanu, N., Negrea, A., Grad, O., Negrea, P., Minzatu, V. & Ardean, C., A new adsorbent for arsenic removal from water, WIT Transactions on Ecology and the Environment, 228, pp. 111–120, 2018.
[32] Hassan, H.S., Attallah, M.F. & Yakout, S.M., Sorption characteristics of an economical sorbent material used for removal radioisotopes of cesium and europium, Journal of Radioanalytical and Nuclear Chemistry, 286, pp. 17–26, 2010.
[33] Gabor, A., Davidescu, C.M., Negrea, A., Ciopec, M., Muntean, C., Negrea, P., Ianasi,
C. & Butnariu, M., Magnesium silicate doped with environmentally friendly extractants used for rare earth elements adsorption, Desalinitation and water treatment, 63, pp. 124–134, 2017.
[34] El-Khaiary, M.I. & Malash, G.F., Common data analysis errors in batch adsorption studies, Hydrometallurgy, 105, pp. 314–320, 2011.
[35] Foo, K.Y. & Hameed, B.H., Insights into the modelling of adsorption isotherm systems, Chemical Engineering Journal. 156, 2–10, 2010.
[36] Alberti, G., Amendola, V., Pesavento, M. & Biesuz, R., Beyond the synthesis of novel solid phases: review on modelling of sorption phenomena, Coordination Chemistry Reviews, 256, pp. 28–45, 2012.
[37] Langmuir, I., The adsorption of gases on plane surfaces of glass, mica and platinum, Journal of the American Chemical Society, 40(9), pp. 1361–1403, 1918.
[38] Freundlich, H.M.F., Uber die adsorption in losungen, Zeitschrift für Physikalische Chemie. 57, pp. 385–470, 1906.
[39] Sips, R., On the structure of a catalyst surface, The Journal of Physical Chemistry, 16, pp. 490–495, 1948.
[40] Negrea A., Ciopec M., Negrea P., Lupa L., Popa A., Davidescu C. M. & Ilia G., Separa-tion of AsV from aqueous solutions using chelating polymers containing FeIII- loaded phosphorus groups, Open Chemistry, 13, pp. 105–112, 2015
[41] Gabor A., Davidescu C.M., Negrea A., Ciopec M. & Lupa L., Behaviour of silica and florisil as solid supports in the removal process of As(V) from aqueous solutions, Journal of Analytical Methods in Chemistry, pp. 1–9, 2015.
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Open Access
Research article

Arsenic Removal from Water Using a New Class of Materials with Adsorbent Properties

Mihaela Ciopec1,
Iosif Hulka2,
Narcis Duteanu1,
Adina Negrea1,
Oana Grad2,
Petru Negrea1,
Vasile Minzatu1,
Cristina Ardean1
1
Politehnica University Timisoara, Faculty of Industrial Chemistry and Environmental Engineering, Romania
2
Research Institute of Renewable Energy of Politehnica University Timisoara, Romania
International Journal of Environmental Impacts
|
Volume 3, Issue 1, 2020
|
Pages 56-68
Received: N/A,
Revised: N/A,
Accepted: N/A,
Available online: 01-21-2020
View Full Article|Download PDF

Abstract:

One of the strategies for sustainable development is to promote a quality health care system, available to all without discrimination, and improving protection against health threats. In this context, arsenic removal from groundwater for drinking purposes presents challenges at national and global levels. Thus, the present article focuses on removing arsenic from groundwaters by using a new class of materials based on cellulose modified with crown ether (dibenzo-18-crown-6) doped with iron ions. Using such extractants involves only a small amount of crown ether, indicating higher efficiency of produced material, and in order to improve the adsorbent properties and selectivity for arsenic removal, the modified cellulose was functionalized with iron ions. The new adsorbent material was characterized by using energy-dispersive X-ray analysis and Fourier-transform infrared spectroscopy. To investigate its adsorption properties for arsenic removal, equilibrium, kinetic and thermodynamic studies were performed. Arsenic adsorption from water onto new class of adsorbent material was studied under different experimental conditions such as reac- tion time, initial arsenic concentration and temperature. Kinetic of adsorption process was better de- scribed by pseudo-second-order model. The equilibrium adsorption data were well described by the Sips adsorption isotherm. The values of thermodynamic parameters (ΔGº, ΔHº, ΔSº) showed that the adsorption process was endothermic and spontaneous. The possibility of reuse of the adsorbent material through adsorption and desorption cycles was also studied, and it was found that the material can be used in three adsorption–desorption cycles.

Keywords: Crown Ethers, Arsenic, Adsorption, Iron Ions, Water
Acknowledgments

This work was supported by research grants PCD-TC-2017.

References
[1] Sharf Ilahi Siddiqui, S.A.C., Iron oxide and its modified forms as an adsorbent for ar-senic removal: A comprehensive recent advancement. Process Safety and Environment Protection, 111, pp. 592–626, 2017.
[2] Kao, A.C., Chu, Y.J., Hsu, F.L. & Liao, V.H.C., Removal of arsenic from groundwater by using a native isolated arsenite-oxidizing bacterium. Journal of Contaminant Hy-drology, 155, pp. 1–8, 2013.
[3] Ng, J.C., Wang, J. & Shraim, A., Global health problems caused by arsenic from natural sources. Chemosphere, 52, pp. 1353–1359, 2003.
[4] *** WHO, Arsenic in drinking water, World Health Organization, 2011 http://www. who.int/water_sanitation_health/dwq/chemicals/arsenic.pdf (accessed 30 November 2017).
[5] Ramesh, A., Hasegawa, H., Maki, T. & Ueda, K., Adsorption of inorganic and organic arsenic from aqueous solutions by polymeric Al/Fe modified montmorillonite. Separa-tion and Purification Technology, 56, pp. 90–100,2007.
[6] Guo, H., Stuben, D. & Berner, Z., Arsenic removal from water using natural iron min-eral quartz sand columns. Science of the Total Environment, 377, pp. 142–151, 2007.
[7] Kundu, S. & Gupta, A.K., Adsorptive removal of As(III) from aqueous solution using iron oxide coated cement (IOCC): Evaluation of kinetic, equilibrium and thermody-namic models. Separation and Purification Technology, 51, pp. 165–172, 2006.
[8] Borah, D., Satokawa, S., Kato, S. & Kojima, T., Surface–modified carbon black for As(V) removal. Journal of Colloid and Interface Science, 319, pp. 53–62, 2008.
[9] Mohan D. & P.J.C.U., Arsenic removal from water/wastewater using adsorbents—A critical review. Journal of Hazardous Materials, 142(1–2), pp. 1-53, 2007.
[10] Molinari R. & A.P., Arsenic removal from water by coupling photocatalysis and com-plexation-ultrafiltration processes: A preliminary study. Water research, 109, pp. 327–336, 2017.
[11] Bora A.J., G.S., Baruah G. & Dutta R.K., Utilization of co-existing iron in arsenic removal from groundwater by oxidation-coagulation at optimizated pH. Journal of En-vironmental Chemical Engineering, 4, pp. 2683–2691, 2016.
[12] Banerji T. & C.S., Arsenic removal from drinking water by electrocoagulation using iron electrodes – an understanding of the process parameters. Journal of Environmental Chemical Engineering, 4, pp. 3990–4000, 2016.
[13] Ji J., Y.Y., Zenga Z., Wanga R., Zhenga X., Deng L. & Li C., Preparation and arse-nic adsorption assessment of PPESK ultrafiltration membranes with organic/inorganic additives. Applied Surface Science, 351, pp. 715–724, 2015.
[14] Zhao D., Y.Y., Wang C. & Chen J.P., Zirconium/PVA modified flat-sheet PVDF mem-brane as a cost-effective adsorptive and filtration material: A case study on decon-tamination of organic arsenic in aqueous solutions. Journal of Colloid and Interface Science, 477, pp. 191–200, 2016.
[15] Salazar H., N.-P.J., Correia D.M., Cardoso V.F., Gonçalves R., Martins P.M., Ferdov S., Martins M.D., Botelho G. & Lanceros-Méndez S., Selective separation of elements from complex solution matrix with molecular recognition plus macrocycles attached to a solid-phase: A review. Materials Chemistry and Physics, 183, pp. 430–434, 2016.
[16] Lee C.G., A.P.J.J., Nam A., Park S.J., Do T., Choi U.S. & Lee S.H., Arsenic(V) removal using an amine-doped acrylic ion exchange fiber: Kinetic, equilibrium, and regenera-tion studies. Journal of Hazardous Materials, 123(1–3), pp. 223–229, 2017.
[17] Dhoble R. M. , M.P.R., Rayalu S. S., Bhole A.G. , Dhoble A. S. & Dhoble S. R., Removal of arsenic(III) from water by magnetic binary oxide particles (MBOP): Experimental studies on fixed bed column. Journal of Hazardous Materials, Part B, pp. 469–478, 2017.
[18] Vithanage M., H.I., Joseph S., Bundschuh J., Bolan N., Ok Y.S., Kirkham M.B. & Rinklebe J., Interaction of arsenic with biochar in soil and water: A critical review. Carbon, 113, pp. 219–230, 2017.
[19] Suda A. & T.M., Functional effects of manganese and iron oxides on the dynamics of trace elements in soils with a special focus on arsenic and cadmium: A review. Geoderma, 270, pp. 68–75, 2016.
[20] Lata S. & S.S.R., Removal of arsenic from water using nano adsorbents and challenges: A review. Journal of Environmental Management, 166, pp. 387–406 2016.
[21] Rahim M., H.M.R. & Haris M., Application of biopolymer composites in arsenic removal from aqueous medium: A review. Journal of Radiation Research and Applied Sciences, 8, pp. 255–263, 2015.
[22] Roy P., M.N.K. & Das K., Geochemistry and arsenic behaviour in groundwater re-sources of the Pannonian Basin (Hungary and Romania). Applied Geochemistry, 26(1), pp. 1–17, 2014.
[23] Abdel-Halim, E.S. & Al-Deyab S.S., Removal of heavy metals from their aqueous solutions through adsorption onto natural polymers. Carbohydrate Polymers, 84(1), pp. 454–458, 2011.
[24] Huang, Z., et al., A novel biodegradable β-cyclodextrin-based hydrogel for the removal of heavy metal ions. Carbohydrate Polymers, 97(2), pp. 496–501, 2013.
[25] Podder, M.S. & Majumder C.B., Bacteria immobilization on neem leaves/MnFe2O4 composite surface for removal of As(III) and As(V) from wastewater. Arabian Journal of Chemistry, 2015.
[26] Sheng, T., et al., Development, characterization and evaluation of iron-coated honey-comb briquette cinders for the removal of As(V) from aqueous solutions. Arabian Jour-nal of Chemistry, 7(1), pp. 27–36, 2014.
[27] Lavoine, N., et al., Microfibrillated cellulose – Its barrier properties and applications in cellulosic materials: A review. Carbohydrate Polymers, 90(2), pp. 735–764, 2012.
[28] Šimkovic, I., Unexplored possibilities of all-polysaccharide composites. Carbohydrate Polymers, 95(2), pp. 697–715, 2013.
[29] Schwaminger, S.P., et al., Nature of Interactions of Amino Acids with Bare Magnetite Nanoparticles. Journal of Physical Chemistry C, 119(40), pp. 23032–23041, 2015.
[30] Negrea, A., Popa, A., Ciopec, M., Lupa, L., Negrea, P., Davidescu, C. M., Motoc, M. & Mînzatu, V., Phosphonium grafted styrene–diviniylbenzene resins impregnated with iron (III) and crown ethers for arsenic removal, Pure and Applied Chemistry, 86(11), pp. 1729–1740, 2014.
[31] Ciopec, M., Hulka, I., Duţeanu, N., Negrea, A., Grad, O., Negrea, P., Minzatu, V. & Ardean, C., A new adsorbent for arsenic removal from water, WIT Transactions on Ecology and the Environment, 228, pp. 111–120, 2018.
[32] Hassan, H.S., Attallah, M.F. & Yakout, S.M., Sorption characteristics of an economical sorbent material used for removal radioisotopes of cesium and europium, Journal of Radioanalytical and Nuclear Chemistry, 286, pp. 17–26, 2010.
[33] Gabor, A., Davidescu, C.M., Negrea, A., Ciopec, M., Muntean, C., Negrea, P., Ianasi,
C. & Butnariu, M., Magnesium silicate doped with environmentally friendly extractants used for rare earth elements adsorption, Desalinitation and water treatment, 63, pp. 124–134, 2017.
[34] El-Khaiary, M.I. & Malash, G.F., Common data analysis errors in batch adsorption studies, Hydrometallurgy, 105, pp. 314–320, 2011.
[35] Foo, K.Y. & Hameed, B.H., Insights into the modelling of adsorption isotherm systems, Chemical Engineering Journal. 156, 2–10, 2010.
[36] Alberti, G., Amendola, V., Pesavento, M. & Biesuz, R., Beyond the synthesis of novel solid phases: review on modelling of sorption phenomena, Coordination Chemistry Reviews, 256, pp. 28–45, 2012.
[37] Langmuir, I., The adsorption of gases on plane surfaces of glass, mica and platinum, Journal of the American Chemical Society, 40(9), pp. 1361–1403, 1918.
[38] Freundlich, H.M.F., Uber die adsorption in losungen, Zeitschrift für Physikalische Chemie. 57, pp. 385–470, 1906.
[39] Sips, R., On the structure of a catalyst surface, The Journal of Physical Chemistry, 16, pp. 490–495, 1948.
[40] Negrea A., Ciopec M., Negrea P., Lupa L., Popa A., Davidescu C. M. & Ilia G., Separa-tion of AsV from aqueous solutions using chelating polymers containing FeIII- loaded phosphorus groups, Open Chemistry, 13, pp. 105–112, 2015
[41] Gabor A., Davidescu C.M., Negrea A., Ciopec M. & Lupa L., Behaviour of silica and florisil as solid supports in the removal process of As(V) from aqueous solutions, Journal of Analytical Methods in Chemistry, pp. 1–9, 2015.
Cite this:
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BibTex Style
MLA Style
Chicago Style
GB-T-7714-2015
Ciopec, M., Hulka, I., Duteanu, N., Negrea, A., Grad, O., Negrea, P., Minzatu, V., & Ardean, C. (2020). Arsenic Removal from Water Using a New Class of Materials with Adsorbent Properties. Int. J. Environ. Impacts., 3(1), 56-68. https://doi.org/10.2495/EI-V3-N1-56-68
M. Ciopec, I. Hulka, N. Duteanu, A. Negrea, O. Grad, P. Negrea, V. Minzatu, and C. Ardean, "Arsenic Removal from Water Using a New Class of Materials with Adsorbent Properties," Int. J. Environ. Impacts., vol. 3, no. 1, pp. 56-68, 2020. https://doi.org/10.2495/EI-V3-N1-56-68
@research-article{Ciopec2020ArsenicRF,
title={Arsenic Removal from Water Using a New Class of Materials with Adsorbent Properties},
author={Mihaela Ciopec and Iosif Hulka and Narcis Duteanu and Adina Negrea and Oana Grad and Petru Negrea and Vasile Minzatu and Cristina Ardean},
journal={International Journal of Environmental Impacts},
year={2020},
page={56-68},
doi={https://doi.org/10.2495/EI-V3-N1-56-68}
}
Mihaela Ciopec, et al. "Arsenic Removal from Water Using a New Class of Materials with Adsorbent Properties." International Journal of Environmental Impacts, v 3, pp 56-68. doi: https://doi.org/10.2495/EI-V3-N1-56-68
Mihaela Ciopec, Iosif Hulka, Narcis Duteanu, Adina Negrea, Oana Grad, Petru Negrea, Vasile Minzatu and Cristina Ardean. "Arsenic Removal from Water Using a New Class of Materials with Adsorbent Properties." International Journal of Environmental Impacts, 3, (2020): 56-68. doi: https://doi.org/10.2495/EI-V3-N1-56-68
Ciopec M.， Hulka I.， Duteanu N.， et al. Arsenic Removal from Water Using a New Class of Materials with Adsorbent Properties[J]. International Journal of Environmental Impacts， 2020， 3(1)： 56-68. https://doi.org/10.2495/EI-V3-N1-56-68